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Science · Advanced Physics
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17.3-4. Suppose the adsorption model to a two by be assuming adsorbed molecules on the same site interact in a vibrational mode of frequency w. Thus the energy of an empty site is zero, the energy of a singly occupied site is Eh, and the energy of a doubly occupied site can take any of the values nhu, with n 0,1,2,... Calculate a) The grand canonical partition sum b) he grand canonical potential c) The mean occupation number, as computed directly from (a) d) The mean occupation number, as computed directly from (b) e) The probability that the system is in the state with n 2 and n- 3 Answer: Denoting E by E Be2 Be (b) Bhu 1 e Bhu (c, d) BE 2 e BA)(1 e Be (e)
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